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                <p style="text-align: center"><img src="/data/upload/202005/1590629704148194.jpg" title="陕西甲醇燃料" alt="陕西甲醇燃料" width="800" height="587" border="0" vspace="0" style="width: 800px; height: 587px;"/></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><a href="/" target="_self"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;"><a href="/" target="_blank" class="key_tag"><font><strong>陕西甲醇燃料</strong></font></a></span></a></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">甲醇（Methanol，CH3OH）是结构简单的饱和一元醇，CAS号为67-56-1或170082-17-4，分子量为32.04，沸点为64.7℃。因在干馏木材中发现，故又称“木醇”或“木精”。是无色有酒精气味易挥发的液体。人口服中毒低剂量约为100mg/kg体重，经口摄入0.3～1g/kg可致死。用于制造甲醛和农药等，并用作有机物的萃取剂和酒精的变性剂等。成品通常由一氧化碳与氢气反应制得。</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">甲醇由甲基和羟基组成的，具有醇所具有的化学性质。</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><a href="/" target="_self"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">甲醇</span></a><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">可以与氟气、纯氧等气体发生反应，在纯氧中剧烈燃烧，生成水蒸气和二氧化碳</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">2CH3OH+3O2=2CO2+4H2O</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">而且，甲醇还可以发生氨化反应（370℃～420℃）</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">NH3+CH3OH→CH3NH2+H2O</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">NH3+2CH3OH→(CH3)2NH+2H2O</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">NH3+3CH3OH→(CH3)3N+3H2O</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">甲醇具有饱和一元醇的通性，由于只有一个碳原子，因此有其反应。例如</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">① 与氯化钙形成结晶状物质CaCl2·4CH3OH，与氧化钡形成BaO·2CH3OH的分子化合物并溶解于甲醇中；类似的化合物有MgCl2·6CH3OH、CuSO4·2CH3OH、CH3OK·CH3OH、AlCl3·4CH3OH、AlCl3·6CH3OH、AlCl3·10CH3OH等</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">4CH3OH+CaCl2→CaCl2·4CH3OH</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">2CH3OH+BaO→2CH3OH·BaO</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">② 与其他醇不同，由于-CH2OH基与氢结合，氧化时生成的甲酸进一步氧化为CO2</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">2CH3OH+O2→2HCHO+2H2O</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">2HCHO+O2→2HCOOH</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">2HCOOH+O2→2H2O+2CO2</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">③ 甲醇与氯、溴不易发生反应，但易与其水溶液作用，初生成二氯甲醚(CH2Cl)2O，因水的作用转变成HCHO与HCl</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">2CH3OH+2Cl2=(CH2Cl)2O+H2O+2HCl</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">(CH2Cl)2O+H2O=2HCHO+2HCl</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">④ 与碱、石灰一起加热，产生氢气并生成甲酸钠</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">CH3OH+NaOH→HCOONa+2H2</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">⑤ 与锌粉一起蒸馏，发生分解，生成CO和H2O [2]&nbsp;</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">计算化学数据</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">1.疏水参数计算参考值（XlogP）：-0.5</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">2.氢键供体数量：1</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">3.氢键受体数量：1</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">4.互变异构体数量：无</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">5.拓扑分子表面积20.2</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">6.重原子数量：2</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">7.复杂度：2</span></p><p style="white-space: normal; text-indent: 2em; line-height: 2em;"><span style="font-size: 14px; font-family: 微软雅黑, &quot;Microsoft YaHei&quot;;">8.共价键单元数量：1</span></p><p><br/></p>
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